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102 245. From a table of experimentally determined values of ei- ther Keq or фGф, we can see at a glance which reactions tend to go to completion and which do not. 010 0. ПппPPh3 n-C13H27CHO 91 yield; all Z ппппп11 ппппOO OO ппппH PPh3 O H O ппп пппппппппппппппппEtOO H EtOO CHO O H O ппппппO PPh3 O OHC EtO2C OO OO Z only пппппппппппппппEtO 96 yield, all E AcO ппAcO OH OH ппппппPPh3 HOHCO OO O H E selective пO ппппппппппппWe can divide ylids into two types those with conjugating or anion-stabilizing substituents adjacent to the negative charge (such as carbonyl groups) and those without.
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